Paul听Ziemann
- Professor
- Institute Fellow, CIRES
- CHEMISTRY
- COOPERATIVE INSTITUTE FOR RESEARCH IN ENVIRONMENTAL SCIENCES (CIRES)

Education
Ph.D.:听Penn State, 1991
Areas of Expertise
Aerosols & Clouds, Instrument Development, Trace Gases & Radicals, Environmental Chemistry, Atmospheric/Astrochemistry
Awards and Honors
- 2017: Fellow, American Association for Aerosol Research
- 2001: Kenneth T. Whitby Award, American Association for Aerosol Research
The primary focus of our group's research is to elucidate mechanisms by which volatile organic compounds emitted from biogenic and anthropogenic sources react in the atmosphere to form products that can create submicron-size organic aerosol particles. These reactions are complex and include photochemistry, gas-phase oxidation, and heterogeneous/multiphase reactions. The resulting particles affect global climate, visibility, and human health. We conduct experiments in large-volume environmental chambers under simulated atmospheric conditions and then identify and quantify organic gas and aerosol reaction products using a variety of analytical instruments and methods. This information is used to develop detailed, quantitative chemical reaction mechanisms for predicting organic aerosol formation, which can be used to improve air quality and global climate models.听We also conduct laboratory, field, and modeling studies of indoor air chemistry.
- Finewax, Z., Jimenez, J.L., Ziemann, P.J., 2020. Development and application of a low-cost vaporizer for rapid, quantitative, in situ addition of organic gases and particles to an environmental chamber. Aerosol Science and Technology, 54, 1567鈥1578.听
- Liu, X, Day, D.A., Krechmer, J.E., Ziemann, P.J., Jimenez, J.L., 2021. Determining activity coefficients of SOA from isothermal evaporation in a laboratory chamber. Environmental Science and Technology Letters, 8, 212鈥217.
- Deming, B.L., Ziemann, P.J., 2021. Measurements of the partitioning of nitric acid and sulfuric acid in aqueous/organic phase-separated systems. Environmental Science: Atmospheres, 1, 93鈥103.听
- Bakker-Arkema, J.G., Ziemann, P.J., 2021. Minimizing errors in measured yields of particle-phase products formed in environmental chamber reactions: Revisiting the yields of b-hydroxynitrates formed from 1-alkene + OH/NOx reactons. ACS Earth and Space Chemistry, 5, 690鈥702.听
- Claflin, M.S., Liu, J., Russell, L.M., Ziemann, P.J., 2021. Comparison of methods of functional group analysis using results from laboratory and field aerosol measurements. Aersosol Science and Technology, 55, 1042鈥1058.听
- Bakker-Arkema, J.G., Ziemann, P.J., 2021. Comprehensive analysis of products and the development of a quantitative mechanism for the OH radical-initiated oxidation of 1-alkenes in the presence of NOx. Journal of Physical Chemistry A, 125, 5829鈥5840.听
- Price, D.J., Day, D.A., Pagonis, D., Stark, H., Handschy, A.V., Algrim, L.B., Miller, S.L., de Gouw, J.A., Ziemann, P.J., Jimenez, J.L., 2021. Sources of gas-phase species in an art museum from comprehensive real-time measurements. ACS Earth and Space Chemistry, 5, 2252鈥2267.听
- DeVault, M.P., Ziemann, P.J., 2021. Gas- and particle-phase products and their mechanisms of formation from the reaction of d-3-carene with NO3 radicals. Journal of Physical Chemistry A, 125, 10207鈥10222.听
- DeVault, M.P., Ziola, A. C., Ziemann, P.J., 2022. Products and mechanisms of secondary organic aerosol formation from the NO3 radical-initiated oxidation of cyclic and acyclic monoterpenes. ACS Earth and Space Chemistry, 6, 2076鈥2092.听
- Kasparoglu, S., Perkins, R., Ziemann, P.J., DeMott, P.J., Kreidenweis, S.M., Finewax, Z., Deming, B.K., DeVault, M.P.,Petters, M.D., 2022. Experimental determination of the relationship between organic aerosol viscosity and ice nucleation at upper free tropospheric conditions. Journal of Geophysical Research: Atmospheres, 127, e2021JD036296.听
- DeVault, M.P., Ziola, A. C., Ziemann, P.J., 2022. Chemistry of secondary organic aerosol formation from reactions of monoterpenes with OH radicals in the presence of NOx. Journal of Physical Chemistry A, 126, 7719鈥7736.听
- Maben, H.K., Ziemann, P.J., 2023. Kinetics of oligomer-forming reactions involving the major functional groups present in atmospheric secondary organic aerosol particles. Environmental Science: Processes and Impacts, 25, 214鈥228.听
- Ranney, A.P., Longnecker, E.R., Ziola, A.C., Ziemann, P.J., 2023. Measured and modeled secondary organic aerosol products and yields from the reaction of n鈥慼exadecane + OH/NOx. ACS Earth and Space Chemistry, 7, 2295鈥3010.
- Liu, J., Russell, L.M., Ruggeri, G., Takahama, S., Claflin, M.S.,听Ziemann, P.J., Pye, H.O.T., Murphy, B.N., Xu, L., Ng, N.L., McKinney,听K.A., Budisulistiorini, S.H., Bertram, T.H., Nenes. A., Surratt, J.D.,听2018. Regional similarities and NOx-related increases in biogenic听secondary organic aerosol in summertime Southeastern U.S. Journal of听Geophysical Research: Atmospheres, 123, 10620鈥10636.
- Pagonis, D., Ziemann, P.J, 2018. Chemistry of hydroperoxycarbonyls in听secondary organic aerosol, Aerosol Science and Technology, 52,听1178鈥1193.
- Claflin, M.S., Krechmer, J.E., Hu, W., Jimenez, J.-L., Ziemann, P.J.,听2018. Functional group composition of secondary organic aerosol formed听from ozonolysis of a鈥憄inene under high VOC and autoxidation听conditions, ACS Earth and Space Chemistry, 2, 1196鈥1210.
- Petters, S.S., Kreidenweis, S.M., Grieshop, A. P., Ziemann, P.J.,听Petters, M.D., 2019. Temperature鈥 and humidity鈥恉ependent phase states听of secondary organic aerosols. Geophysical Research Letters, 46,1005鈥1013.
- Algrim, L.B., Ziemann, P.J., 2019. Effect of the hydroxyl group on听yields and composition of organic aerosol formed from OH
radical-initiated reactions of alcohols in the presence of NOx.听ACS-Earth and Space Chemistry, 3, 413鈥423. - Claflin, M.S., Ziemann, P.J., 2019. Thermal desorption behavior of听hemiacetal, acetal, ether, and ester oligomers, Aerosol Science and听Technology, 53, 473鈥484.听
- Pagonis, D., Price, D.J., Algrim, L.B., Day, D.A., Handschy, A.V.听Stark, H., Miller, S.L., de Gouw, J., Jimenez, J.L., Ziemann, P.J.,听2019. Time-resolved measurements of indoor chemical emissions,听deposition, and reactions in a university art museum. Environmental听Science and Technology, 53, 4794鈥4802.
- Finewax, Z., de Gouw, J.A., Ziemann, P.J., 2019. Products and听secondary organic aerosol yields from the OH and NO3 radical-initiated听oxidation of resorcinol. ACS-Earth and Space Chemistry, 3,1248鈥1259.
- Liu, X., Deming, B., Pagonis,D., Day, D.A., Palm, B.B., Talukdar, R.,听Roberts, J.M., Veres, P.R., Krechmer, J.E., Thronton, J.A., de Gouw,听J.A., Ziemann, P.J., Jimenez, J.L., 2019. Effects of gas-wall听interactions on measurements of semivolatile compounds and small polar听molecules. Atmospheric Measurement Techniques. 12, 3137鈥3149.
- Deming, B.L., Pagonis,D., Liu, X., Day, D.A., Talukdar, R., Krechmer,听J.E., de Gouw, J., Jimenez, J.L, Ziemann, P.J., 2019. Measurements of听delays of gas-phase compounds in a wide variety of tubing materials听due to gas鈥搘all interactions. Atmospheric Measurement Techniques. 12,听3453鈥3461.
- Pagonis, D., Algrim, L.B., Price, D.J., Day, D.A., Handschy, A.V.,听Stark, H., Miller, S.L., de Gouw, J.A., Jimenez, J.L., Ziemann, P.J.,听2019. Autoxidation of limonene in a university art museum.听Environmental Science and Technology Letters, 6, 520鈥524.
- Liu, X., Day, D.A., Krechmer, J.E., Brown, W., Peng, Z., Ziemann,听P.J., Jimenez, J.L., 2019. Direct measurements of semi-volatile听organic compound dynamics show near-unity mass accommodation听coefficients for diverse aerosols. Communications Chemistry, 2.98.
- Matsunaga, A., Ziemann, P.J., 2019. Branching ratios and rate听constants for decomposition and isomerization of 尾-hydroxyalkoxy听radicals formed from OH radical-initiated reactions of C6鈥揅13听2-methyl-1-alkenes in the presence of NOx. Journal of Physical听Chemistry A, 123, 7839鈥7846.
- Price, D.J., Day, D.A., Pagonis, D., Stark, H., Algrim, L.B.,听Handschy, A.V., Liu, S., Krechmer, J.E., Miller, S.L., Hunter, J.F.,听de Gouw, J.A., Ziemann, P.J., Jimenez, J.L., 2019. The budgets of听organic carbon composition and oxidation in indoor air. Environmental听Science and Technology, 53, 13053鈥13063.
- Bakker-Arkema, J.G., Ziemann, P.J., 2020. Measurements of kinetics and听equilibria for the condensed phase reactions of hydroperoxides with听carbonyls to form peroxyhemiacetals. ACS-Earth and Space Chemistry, 4,听467鈥475.
- Algrim, L.B, Ziemann, P.J., 2020. Effect of the nitrate group on听yields and composition of secondary organic aerosol formed from听reactions of alkyl nitrates with OH radicals in the presence of NOx.听Aerosol Science and Technology, 54, 1070鈥1082.
- Algrim, L.B, Pagonis, D., de Gouw, J.A., Jimenez, J.L., Ziemann, P.J.,听2020. Measurements and modeling of the absorptive partitioning of听volatile organic compounds to painted surfaces. Indoor Air, 30,听745鈥756.
- Deming, B.L., Ziemann, P.J., 2020. Quantification of alkenes on indoor听surfaces and implications for sources and sinks. Indoor Air, 30,听914鈥924.
- Aimanant, S., Ziemann, P.J., 2013. Chemical mechanisms of aging of aerosol formed from the reaction of n-pentadecane with OH radicals in the presence of NOx. Aerosol Science and Technology, 47, 979-990.
- Strollo, C.M., Ziemann, P.J., 2013. Products and mechanism of secondary organic aerosol formation from the reaction of 3-methylfuran with OH radicals in the presence of NOx. Atmospheric Environment, 77, 534-543.
- Yeh, G.K., Ziemann, P.J., 2014. Alkyl nitrate formation from the reactions of C8鈭扖14 n鈥慳lkanes with OH radicals in the presence of NOx:
- Measured yields with essential corrections for gas鈭抴all partitioning. Journal of Physical Chemistry A, 118, 8147-8157.
- Suda, S.R., Petters, M.D., Yeh, G.K., Strollo, C.S., Matsunaga, A., Faulhaber, A., Ziemann, P.J., Prenni, A.J., Carrico, C.M., Sullivan, R.C., Kreidenweis, S.M. 2014. Influence of functional groups on organic aerosol cloud condensation nucleus activity. Environmental Science and Technology, 48, 10182鈥10190.
- Yeh, G.K., Ziemann, P.J., 2014. Identification and yields of 1,4-hydroxynitrates formed from the reactions of C8鈭扖16 n鈥慳lkanes with OH radicals in the presence of NOx. Journal of Physical Chemistry A, 118, 8797-8806.
- Yeh, G. K., Ziemann, P.J., 2015. Gas-wall partitioning of oxygenated organic compounds: Measurements, structure鈥揳ctivity relationships, and correlation with gas chromatographic retention factor. Aerosol Science and Technology, 49, 726-737.
- Yeh, G.K., Claflin, M.S., Ziemann, P.J., 2015. Products and mechanism of the reaction of 1鈥憄entadecene with NO3 radicals and the effect of a 鈭扥NO2 group on alkoxy radical decomposition. Journal of Physical Chemistry A, 119, 10684-10696.
- Strollo, C.M., Ziemann, P.J., 2016. Investigation of the formation of benzoyl peroxide, benzoic anhydride, and other potential aerosol products from gas-phase reactions of benzoylperoxy radicals.
- Atmospheric Environment, 130, 202鈥210.
- Ranney, A.P., Ziemann, P.J., 2016. Microscale spectrophotometric methods for quantification of functional groups in oxidized organic aerosol. Aerosol Science and Technology, 50, 881鈥892.
- Ranney, A.P., Ziemann, P.J., 2016. Kinetics of acid-catalyzed dehydration of cyclic hemiacetals in aerosol particles in equilibrium with nitric acid vapor. Journal of Physical Chemistry A, 120, 2561鈥2568.
- Krechmer, J.E., Pagonis, D., Ziemann, P.J., Jimenez, J.L., 2016. Quantification of gas-wall partitioning in teflon environmental chambers using rapid bursts of low-volatility oxidized species generated in situ. Environmental Science and Technology, 50, 5757鈥5765.
- Algrim, L.B., Ziemann, P.J., 2016. Effect of the keto group on yields and composition of organic aerosol formed from OH radical-initiated reactions of ketones in the presence of NOx. Journal of Physical Chemistry A, 120, 6978鈥6989.
- Liu, S., Li, R., Wild, R.J., Warneke, C., de Gouw, J.A., Brown, S.S., Miller, S.L., Luongo, J.C., Jimenez, J.L., Ziemann, P.J., 2016.Contribution of human-related sources to indoor volatile organic compounds in a university classroom. Indoor Air, 925鈥938.Ranney, A.P., Ziemann, P.J., 2017. Identification and quantification of oxidized organic aerosol compounds using derivatization, liquid chromatography, and chemical ionization mass spectrometry. Aerosol Science and Technology, 51, 342鈥33.
- Liu, S., Thompson, S.L., Stark, H., Ziemann, P.J., Jimenez, J.L., 2017. Gas-phase carboxylic acids in a university classroom: abundance, variability, and sources. Environmental Science and Technology, 51, 5454鈥5463.
- Krechmer, J.E., Day, D.A., Ziemann, P.J., Jimenez, J.L., 2017. Direct measurements of gas/particle partitioning and mass accommodation coefficients in environmental chambers. Environmental Science and Technology, 51, 11867鈥11876.
- Petters, S.S., Pagonis, D., Claflin, M.S., Levin, E.J.T., Petters, M.D., Ziemann, P.J., Kreidenweis, S.M., 2017. Hygroscopicity of organic compounds as a function of carbon chain length and carboxyl, hydroperoxy, and carbonyl functional groups. Journal of Physical Chemistry A, 121, 5164鈥5174.
- Liu, J., Russell, L.M., Lee, A.K.Y., McKinney, K.A., Surratt, J.D., Ziemann, P.J., 2017. Observational evidence for pollution-influenced selective uptake contributing to biogenic secondary organic aerosols in the southeastern U.S. Geophysical Research Letters, 44, 8056鈥8064, doi:10.1002/2017GL074665.
- Pagonis, D., Krechmer, J.E., de Gouw, J., Jimenez, J.L, Ziemann, P.J., 2017. Effects of gas鈥搘all partitioning in Teflon tubing and instrumentation on time-resolved measurements of gas-phase organic compounds. Atmospheric Measurement Techniques, 10, 4687鈥4696.
- Finewax, Z., de Gouw, J.A., Ziemann, P.J., 2018. Identification and听quantification of 4-nitrocatechol formed from OH and NO3听radical-initiated reactions of catechol in air in the presence of NOx:听Implications for secondary organic aerosol formation from biomass听burning. Environmental Science and Technology, 52, 1981鈥1989.
- Claflin, M.S., Ziemann, P.J., 2018. Identification and quantitation of aerosol products of the reaction of 尾-pinene with NO3 radicals and implications for gas- and particle-phase reaction mechanisms. Journal of Physical Chemistry A, 122, 3640鈥3652.